Anquetil-Deck C, Cleaver D J
Laboratoire Chimie Provence, UMR 6264, University of Aix-Marseille I, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France.
Phys Rev E Stat Nonlin Soft Matter Phys. 2010 Sep;82(3 Pt 1):031709. doi: 10.1103/PhysRevE.82.031709. Epub 2010 Sep 27.
Here, we use molecular simulation to consider the behavior of a thin nematic film confined between two identical nanopatterned substrates. Using patterns involving alternating stripes of homeotropic-favoring and homogeneous-favoring substrates, we investigate the influence of the relative stripe width and the film thickness. From this, we show that the polar anchoring angle can be varied continuously from planar to homeotropic by appropriate tuning of these parameters. For very thin films with equal stripe widths, we observe orientational bridging, the surface patterning being written in domains which traverse the nematic film. This dual-bridging-domain arrangement breaks down with increase in film thickness, however, being replaced by a single tilted monodomain. Strong azimuthal anchoring in the plane of the stripe boundaries is observed for all systems.
在此,我们使用分子模拟来研究限制在两个相同纳米图案化基板之间的薄向列相薄膜的行为。通过使用包含垂直取向偏好和均匀取向偏好基板交替条纹的图案,我们研究了相对条纹宽度和薄膜厚度的影响。由此,我们表明,通过适当调整这些参数,极性锚定角可以从平面取向连续变化到垂直取向。对于具有相等条纹宽度的非常薄的薄膜,我们观察到取向桥接,表面图案形成于穿过向列相薄膜的畴中。然而,这种双桥接畴排列随着薄膜厚度的增加而瓦解,取而代之的是单个倾斜的单畴。在所有系统中,我们都观察到条纹边界平面内存在强烈的方位角锚定。