Misharin A Iu, Timofeev V P
Orekhovich Institute of Biomedical Chemistry, Russian Academy of Medical Sciences, Pogodinskaya ul. 10, Moscow, 119992 Russia.
Bioorg Khim. 2004 Jan-Feb;30(1):84-8. doi: 10.1023/b:rubi.0000015777.32627.7f.
Ergosteryl acetate was converted through three stages into 3 beta-acetoxy-24-methyl-5 alpha-cholesta-8(14),22-diene-15-one in 32% overall yield. The product was transformed to 3 beta-hydroxy-24- methyl-5 alpha-cholesta-8(14),22-diene-15-one, 3 alpha-hydroxy-24-methyl-5 alpha-cholesta-8(14),22-diene-15-one, and 24-methyl-5 alpha-cholesta-8(14),22-diene-3,15-dione. The compounds were characterized by 1H and 13C NMR spectra. The English version of the paper: Russian Journal of Bioorganic Chemistry, 2004, vol. 30, no. 1; see also http://www.maik.ru.
乙酸麦角甾醇经三个阶段转化为3β-乙酰氧基-24-甲基-5α-胆甾-8(14),22-二烯-15-酮，总产率为32%。该产物被转化为3β-羟基-24-甲基-5α-胆甾-8(14),22-二烯-15-酮、3α-羟基-24-甲基-5α-胆甾-8(14),22-二烯-15-酮和24-甲基-5α-胆甾-8(14),22-二烯-3,15-二酮。这些化合物通过1H和13C核磁共振谱进行表征。该论文的英文版：《俄罗斯生物有机化学杂志》，2004年，第30卷，第1期；另见http://www.maik.ru 。
