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兽医实验室含甲醛废水的光催化降解

Photocatalytic degradation of formaldehyde containing wastewater from veterinarian laboratories.

作者信息

Araña J, Martínez Nieto J L, Herrera Melián J A, Doña Rodríguez J M, González Díaz O, Pérez Peña J, Bergasa O, Alvarez C, Méndez J

机构信息

Photocatalysis and Electrochemical Laboratory, Parque Científico y Tecnológico, Universidad de Las Palmas de Gran Canaria, Tafira Campus, E-35017 Las Palmas de Gran Canaria, Spain.

出版信息

Chemosphere. 2004 May;55(6):893-904. doi: 10.1016/j.chemosphere.2003.11.060.

Abstract

The photocatalytic destruction of methanol, formaline (mixture of formaldehyde, methanol and water) and formaline wastes from the preservation of vertinarian physiologic samples has been attempted by two different processes, at high concentrations of reagents and by dossification of reagents, varying pH in both. Experiment evolution has been monitored by measuring the organic matter such as TOC and formaldehyde concentrations [H2CO]. Also, methanol and methanol-formaldehyde interactions with the TiO2 surface have been analysed by FTIR spectroscopy. Results indicate that at high concentrations the catalyst surfacial alterations given by methoxy, formates or carbonates, according to the pH of the sample can profoundly affect catalyst behaviour. It has been established that reagent dossification is advantageous for enhancing photonic efficiency as it minimizes the adsorbate presence that hampers the photocatalytic process.

摘要

通过两种不同的方法,在高浓度试剂以及试剂剂量变化、pH值变化的条件下,尝试对甲醇、福尔马林(甲醛、甲醇和水的混合物)以及兽医生理样本保存产生的福尔马林废物进行光催化分解。通过测量总有机碳(TOC)和甲醛浓度[H₂CO]等有机物来监测实验进展。此外,还通过傅里叶变换红外光谱(FTIR)分析了甲醇和甲醇 - 甲醛与二氧化钛表面的相互作用。结果表明,在高浓度下,根据样品的pH值,由甲氧基、甲酸盐或碳酸盐引起的催化剂表面变化会深刻影响催化剂性能。已经确定,试剂剂量变化有利于提高光子效率,因为它能将阻碍光催化过程的吸附物存在降至最低。

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