On/off regulation of catalysis by allosteric control of metal complex nuclearity.
作者信息
Kovbasyuk Larisa, Pritzkow Hans, Krämer Roland, Fritsky Igor O
机构信息
Anorganisch-Chemisches-Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
出版信息
Chem Commun (Camb). 2004 Apr 7(7):880-1. doi: 10.1039/b316225g. Epub 2004 Mar 4.
DOI:10.1039/b316225g
PMID:15045110
Abstract
The nature of the allosteric metal ion M (Pd2+ or Pt2+) in complexes ML of a polytopic ligand controls uptake of additional Cu2+ ions; while [Cu2Pd(L-4H)]2+ is a highly active catalyst for phosphodiester cleavage, [CuPt(L-4H)] is inactive.
摘要
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