• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Ar'Sn(μ-Br)Sn(Ar')CH₂C₆H₄-4-Pri的表征（Ar' = C₆H₃-2,6-Dipp₂；Dipp = C₆H₃-2,6-Pri₂）：一种较重的14族元素单桥联烯烃异构体HM(μ-H)MH₂（M = Sn或Pb）的稳定结构类似物。

Characterization of Ar'Sn(micro-Br)Sn(Ar')CH2C6H4-4-Pri (Ar' = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2): a stable structural analogue for a heavier group 14 element monobridged alkene isomer HM(micro-H)MH2 (M = Sn or Pb).

作者信息

Stanciu Corneliu, Richards Anne F, Power Philip P

机构信息

Department of Chemistry, University of California, Davis, California, USA.

出版信息

J Am Chem Soc. 2004 Apr 7;126(13):4106-7. doi: 10.1021/ja0316871.

DOI:10.1021/ja0316871
PMID:15053590
Abstract

The title compound is the first stable structural analogue for the monobridged isomer of a heavier group 14 alkene analogue.

摘要

标题化合物是较重的第14族烯烃类似物的单桥异构体的首个稳定结构类似物。

相似文献

1
Characterization of Ar'Sn(micro-Br)Sn(Ar')CH2C6H4-4-Pri (Ar' = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2): a stable structural analogue for a heavier group 14 element monobridged alkene isomer HM(micro-H)MH2 (M = Sn or Pb).Ar'Sn(μ-Br)Sn(Ar')CH₂C₆H₄-4-Pri的表征（Ar' = C₆H₃-2,6-Dipp₂；Dipp = C₆H₃-2,6-Pri₂）：一种较重的14族元素单桥联烯烃异构体HM(μ-H)MH₂（M = Sn或Pb）的稳定结构类似物。
J Am Chem Soc. 2004 Apr 7;126(13):4106-7. doi: 10.1021/ja0316871.
2
Isomeric forms of divalent heavier group 14 element hydrides: characterization of Ar'(H)GeGe(H)Ar' and Ar'(H)(2)GeGeAr'.PMe(3) (Ar' = C(6)H(3)-2,6-Dipp(2); Dipp = C(6)H(3)-2,6-Pr(i)(2)).二价较重14族元素氢化物的异构体形式：Ar'(H)GeGe(H)Ar'和Ar'(H)₂GeGeAr'.PMe₃的表征（Ar' = C₆H₃-2,6-Dipp₂；Dipp = C₆H₃-2,6-Prⁱ₂）
J Am Chem Soc. 2003 Mar 19;125(11):3204-5. doi: 10.1021/ja029772g.
3
Reactions of the heavier group 14 element alkyne analogues Ar'EEAr' (Ar' = C6H3-2,6(C6H3-2,6-Pri2)2; E = Ge, Sn) with unsaturated molecules: probing the character of the EE multiple bonds.较重的第14族元素炔类似物Ar'EEAr'（Ar' = C6H3-2,6(C6H3-2,6-Pri2)2；E = Ge，Sn）与不饱和分子的反应：探究EE重键的性质
J Am Chem Soc. 2005 Dec 14;127(49):17530-41. doi: 10.1021/ja055372s.
4
Synthesis and characterization of the monomeric imides Ar'MNAr' ' (M = Ga or In; Ar' or Ar' ' = terphenyl ligands) with two-coordinate gallium and indium.具有二配位镓和铟的单体酰亚胺Ar'MNAr''（M = Ga或In；Ar'或Ar'' = 三联苯配体）的合成与表征
J Am Chem Soc. 2003 Feb 19;125(7):1694-5. doi: 10.1021/ja029422u.
5
Different reactivity of the heavier group 14 element alkyne analogues Ar'MMAr' (M = Ge, Sn; Ar' = C6H3-2,6(C6H3-2,6-Pri2)2) with R2NO.较重的第14族元素炔烃类似物Ar'MMAr'（M = Ge，Sn；Ar' = C6H3-2,6（C6H3-2,6-Pri2）2）与R2NO的不同反应活性。
Chem Commun (Camb). 2005 Dec 28(48):6041-3. doi: 10.1039/b513189h. Epub 2005 Nov 9.
6
Quasi-isomeric gallium amides and imides GaNR2 and RGaNR (R = organic group): reactions of the digallene, Ar'GaGaAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2) with unsaturated nitrogen compounds.准异构体镓酰胺和亚胺GaNR₂及RGaNR（R = 有机基团）：二镓烯Ar'GaGaAr'（Ar' = C₆H₃-2,6-(C₆H₃-2,6-Pri₂)₂）与不饱和氮化合物的反应
J Am Chem Soc. 2006 Sep 27;128(38):12498-509. doi: 10.1021/ja063072k.
7
Why the mechanisms of digermyne and distannyne reactions with H2 differ so greatly.为什么双锗烷和双锡烷与 H2 的反应机理有如此大的差异。
J Am Chem Soc. 2012 May 30;134(21):8856-68. doi: 10.1021/ja300111q. Epub 2012 May 17.
8
The [2 + 4] Diels-Alder cycloadditon product of a probable dialuminene, Ar'AlAlAr' (Ar' = C(6)H(3)- 2,6-dipp(2); dipp = C(6)H(3)-2,6-Pr(i)(2)), with toluene.一种可能的二铝烯Ar'AlAlAr'（Ar' = C(6)H(3)-2,6 - dipp(2)；dipp = C(6)H(3)-2,6 - Pr(i)(2)）与甲苯的[2 + 4]狄尔斯-阿尔德环加成产物。
J Am Chem Soc. 2003 Sep 10;125(36):10784-5. doi: 10.1021/ja034478p.
9
Synthesis, structural characterization, and spectroscopy of the cadmium-cadmium bonded molecular species Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2).镉-镉键合分子物种Ar'CdCdAr'（Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2）的合成、结构表征及光谱分析
J Am Chem Soc. 2006 Nov 29;128(47):15068-9. doi: 10.1021/ja066108h.
10
Reactivity of Ar'GeGeAr' (Ar' = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) toward alkynes: isolation of a stable digermacyclobutadiene.Ar'GeGeAr'（Ar' = C6H3-2,6-Dipp2，Dipp = C6H3-2,6-iPr2）与炔烃的反应活性：稳定的二锗环丁二烯的分离
J Am Chem Soc. 2004 Apr 28;126(16):5062-3. doi: 10.1021/ja0318481.