Rekik Walid, Naïli Houcine, Mhiri Tahar
Département de Chimie, Faculté des Sciences de Sfax, BP 802, 3018 Sfax, Tunisia.
Acta Crystallogr C. 2004 Apr;60(Pt 4):i50-2. doi: 10.1107/S0108270104004603. Epub 2004 Mar 31.
Potassium gadolinium polyphosphate, KGd(PO(3))(4), was synthesized using the flux method. The atomic arrangement consists of an infinite long-chain polyphosphate organization. Two types of chains, with a period of eight PO(4) tetrahedra, run along the [101] direction. The Gd atoms have an eightfold coordination, while the K atoms have nine O-atom neighbours.
采用助熔剂法合成了多磷酸钆钾(KGd(PO(3))(4))。其原子排列由无限长链状的多磷酸盐结构组成。两种链沿着[101]方向延伸,周期为八个PO(4)四面体。钆原子具有八配位,而钾原子有九个氧原子邻位。