• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

μ-乙烷-1,2-二基双（二苯基氧化膦）-κ(2)O:O'-双[二苄基二氯化锡(IV)]：一种含有三角双锥构型锡(IV)的中心对称配合物，通过C-H·π(芳烃)氢键连接成环链。

Micro-ethane-1,2-diylbis(diphenylphosphine oxide)-kappa(2)O:O'-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H.pi(arene) hydrogen bonds.

作者信息

Mohamed E Mothi, Panchanatheswaran Krishnaswamy, Low John N, Glidewell Christopher

机构信息

Department of Chemistry, Bharathidasan University, Tiruchirappalli, Tamil Nadu 620 024, India.

出版信息

Acta Crystallogr C. 2004 Apr;60(Pt 4):m172-3. doi: 10.1107/S0108270104003981. Epub 2004 Mar 11.

DOI:10.1107/S0108270104003981
PMID:15071208
Abstract

The title compound, [Sn(2)Cl(4)(C(7)H(7))(4)(C(26)H(24)O(2)P(2))], (I), was isolated from the reaction of 1,2-bis(diphenylphosphino)ethane with dibenzyltin(IV) dichloride in the presence of air. The molecules of (I) lie across centres of inversion in space group C2/c and contain five-coordinate Sn atoms. The molecules are linked into chains of rings by a single C-H.pi(arene) hydrogen bond.

摘要

标题化合物[Sn₂Cl₄(C₇H₇)₄(C₂₆H₂₄O₂P₂)]，(I)，是在空气中由1,2-双(二苯基膦基)乙烷与二苄基二氯化锡(IV)反应分离得到的。(I)的分子位于空间群C2/c的对称中心上，包含五配位的Sn原子。分子通过单个C-H·π(芳烃)氢键连接成环链。

相似文献

1
Micro-ethane-1,2-diylbis(diphenylphosphine oxide)-kappa(2)O:O'-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H.pi(arene) hydrogen bonds.μ-乙烷-1,2-二基双（二苯基氧化膦）-κ(2)O:O'-双[二苄基二氯化锡(IV)]：一种含有三角双锥构型锡(IV)的中心对称配合物，通过C-H·π(芳烃)氢键连接成环链。
Acta Crystallogr C. 2004 Apr;60(Pt 4):m172-3. doi: 10.1107/S0108270104003981. Epub 2004 Mar 11.
2
pi-Stacked hydrogen-bonded sheets in N,N'-bis(4-nitrobenzylidene)ethane-1,2-diamine and pi-stacked hydrogen-bonded chains in N,N'-bis(4-nitrobenzylidene)propane-1,3-diamine.
Acta Crystallogr C. 2005 Jan;61(Pt 1):o53-6. doi: 10.1107/S0108270104030719. Epub 2004 Dec 18.
3
Hydrogen-bonded adducts of triphenylsilanol with diamines: a finite ten-molecule aggregate, and chain, sheet and framework structures built from O-H...O, O-H...N and C-H...pi(arene) hydrogen bonds.三苯基硅醇与二胺的氢键加合物：一种有限的十分子聚集体，以及由O-H...O、O-H...N和C-H...π(芳烃)氢键构建的链状、片状和骨架结构。
Acta Crystallogr B. 2004 Apr;60(Pt 2):238-48. doi: 10.1107/S0108768104002344. Epub 2004 Mar 18.
4
Isomers and polymorphs of (E,E)-1,4-bis(nitrophenyl)-2,3-diaza-1,3-butadienes.
Acta Crystallogr B. 2006 Aug;62(Pt 4):666-75. doi: 10.1107/S010876810601439X. Epub 2006 Jul 12.
5
Nine N-aryl-2-chloronicotinamides: supramolecular structures in one, two and three dimensions.九种N-芳基-2-氯烟酰胺：一维、二维和三维超分子结构
Acta Crystallogr B. 2006 Aug;62(Pt 4):651-65. doi: 10.1107/S0108768106015497. Epub 2006 Jul 12.
6
Hydrogen-bonded dimers, chains and rings in six differently substituted 2-vinyltetrahydro-1,4-epoxy-1-benzazepines.六种不同取代的2-乙烯基四氢-1,4-环氧-1-苯并氮杂卓中的氢键二聚体、链和环。
Acta Crystallogr C. 2010 Apr;66(Pt 4):o209-14. doi: 10.1107/S0108270110009017. Epub 2010 Mar 16.
7
Manganese(II) and cobalt(II) complexes of 1,4-bis(diphenylphosphinoyl)butane.
Acta Crystallogr C. 2009 Jan;65(Pt 1):m10-3. doi: 10.1107/S010827010804033X. Epub 2008 Dec 6.
8
catena-Poly[[bis(nitrato-kappa(2)O,O')copper(II)]-mu-propane-1,3-diylbis(diphenylphosphine oxide)-kappa(2)O:O'].
Acta Crystallogr C. 2007 Oct;63(Pt 10):m433-5. doi: 10.1107/S0108270107038711. Epub 2007 Sep 1.
9
Four N(7)-benzyl-substituted 4,5,6,7-tetrahydro-1H-pyrazolo[3,4-b]pyridine-5-spiro-1'-cyclohexane-2',6'-diones as ethanol hemisolvates: similar molecular constitutions but different crystal structures.四种N(7)-苄基取代的4,5,6,7-四氢-1H-吡唑并[3,4-b]吡啶-5-螺-1'-环己烷-2',6'-二酮乙醇半溶剂化物：相似的分子组成但不同的晶体结构。
Acta Crystallogr C. 2008 Dec;64(Pt 12):o637-42. doi: 10.1107/S0108270108036937. Epub 2008 Nov 22.
10
Three-dimensional frameworks built from piperazine-2,5-dione and simple metal salts (M = Co, Ni, Cu and Ag).由哌嗪-2,5-二酮和简单金属盐（M = 钴、镍、铜和银）构建的三维框架结构。
Acta Crystallogr C. 2008 Aug;64(Pt 8):m286-91. doi: 10.1107/S010827010801648X. Epub 2008 Jul 12.

引用本文的文献

1
Tetra-iodido[methyl-enebis(diphenyl-phosphine oxide)-κO:O']tin(IV) chloro-form solvate.四碘化[亚甲基双（二苯基氧化膦）-κO:O']锡(IV) 氯仿溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 7;64(Pt 7):m894. doi: 10.1107/S1600536808013627.