二水合高氯酸铁（II）三[4-（1H-吡唑-3-基）-3-氮杂丁-3-烯基]胺
Tris[4-(1H-pyrazol-3-yl)-3-azabut-3-enyl]amine iron(II) diperchlorate monohydrate.
作者信息
Hardie Michaele J, Kilner Colin A, Halcrow Malcolm A
机构信息
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, England.
出版信息
Acta Crystallogr C. 2004 Apr;60(Pt 4):m177-9. doi: 10.1107/S010827010400407X. Epub 2004 Mar 20.
In the title complex, Fe(C(18)H(24)N(10))(2).H(2)O, the complex cation adopts a capped trigonal antiprismatic stereochemistry, with a long Fe-amine interaction [2.7468 (16) A]. The Fe centre in the asymmetric unit is fully high-spin at 100 K. Hydrogen bonding assembles dimeric units, which are then linked by further hydrogen bonding into chains running parallel to the crystallographic a axis.
在标题配合物Fe(C₁₈H₂₄N₁₀)₂·H₂O中，配合物阳离子呈现出盖帽三角反棱柱立体化学结构，存在长的铁 - 胺相互作用[2.7468 (16) Å]。不对称单元中的铁中心在100 K时完全处于高自旋状态。氢键作用组装形成二聚体单元，这些二聚体单元再通过进一步的氢键作用连接成平行于晶体学a轴的链。
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