H2O2/UV enhanced degradation of pesticides in wastewater.

Photodegradation of organic pesticides in industrial wastewater was examined in a UV/H2O2/air system. An experimentally determined optimal amount of hydrogen peroxide (0.008% v/v) indicates that hydrogen peroxide concentration controlled the efficiency of photodegradation. Pre-treatment operations such as sedimentation, filtration and coagulation were used to obtain better efficiency of pesticide removal and to cut down on irradiation time. Finally, scale-up experiments in the air-sparged hydrocyclone (ASH) reactor were carried out. After 5 min irradiation of 100 dm3 industrial wastewater almost all pesticides were destroyed. Thus the ASH reactor proved to be an effective contactor for carrying out photochemical reactions.