含硼大环与锕系元素形成包合物。
Formation of inclusion organoactinide complexes with boron-containing macrocycles.
作者信息
Barnea Eyal, Andrea Tamer, Kapon Moshe, Eisen Moris S
机构信息
Department of Chemistry and Institute of Catalysis Science and Technology, Technion-Israel Institute of Technology, Haifa.
出版信息
J Am Chem Soc. 2004 Apr 28;126(16):5066-7. doi: 10.1021/ja0498843.
Reaction of the organoactinide complexes (C5Me5)2AnMe2 (An = Th, U) with catecholborane yields an inclusion complex where the actinide is encapsulated inside a 15-membered, hexaoxo, trianionic macrocycle built from alternating catechol and catecholborate fragments. In the presence of LiOH, a dimer of two encapsulated actinide macrocycles is formed. The X-ray molecular structure for all the complexes is presented.
有机锕系配合物（C5Me5）2AnMe2（An = Th，U）与儿茶酚硼烷反应生成一种包合物，其中锕系元素被封装在一个由交替的儿茶酚和儿茶酚硼酸酯片段构建的15元、六氧代、三阴离子大环内。在LiOH存在下，形成了两个封装的锕系大环的二聚体。给出了所有配合物的X射线分子结构。
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