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针铁矿(α-FeOOH)纳米棒水悬浮液的物理性质。第二部分:向列相。

Physical properties of aqueous suspensions of goethite (alpha-FeOOH) nanorods. Part II: In the nematic phase.

作者信息

Lemaire B J, Davidson P, Petermann D, Panine P, Dozov I, Stoenescu D, Jolivet J P

机构信息

Laboratoire de Physique des Solides, UMR CNRS 8502, Université Paris-Sud, 91405, Orsay, France.

出版信息

Eur Phys J E Soft Matter. 2004 Mar;13(3):309-19. doi: 10.1140/epje/i2003-10079-5.

Abstract

At volume fractions larger than 8.5%, aqueous suspensions of lath-like goethite (alpha-FeOOH) nanorods form a lyotropic nematic phase. In this article, we first discuss the nematic ordering within statistical-physics models of the isotropic/nematic phase transition. We then describe the influence of a magnetic field on the nematic phase. Because the nanorods bear permanent magnetic moments, the nematic suspensions have dipolar order and very low Frederiks thresholds. Moreover, the nematic phase aligns parallel to a small magnetic field but realigns perpendicular to a high field because of a competition between the permanent moments of the nanorods and their negative anisotropy of magnetic susceptibility. This magneto-optical study of the nematic phase is completely consistent with that of the isotropic phase of the same suspensions published in Part I (this issue, p. 291). Besides, we demonstrate the field-induced biaxiality of a nematic single domain aligned perpendicular to the field. We also describe here preliminary experiments where an a.c. electric field is applied to the nematic phase. Both field amplitude and frequency were found to control the alignment direction and homeotropic-to-planar alignment transitions were observed. From this data, simple models were used to estimate some physical constants of the nematic phase.

摘要

在体积分数大于8.5%时,板条状针铁矿(α-FeOOH)纳米棒的水悬浮液形成溶致向列相。在本文中,我们首先在各向同性/向列相转变的统计物理模型中讨论向列序。然后我们描述磁场对向列相的影响。由于纳米棒具有永久磁矩,向列悬浮液具有偶极序且弗雷德里克斯阈值非常低。此外,由于纳米棒的永久磁矩与其磁化率的负各向异性之间的竞争,向列相平行于小磁场排列,但垂直于强磁场重新排列。这种对向列相的磁光研究与第一部分(本期,第291页)发表的相同悬浮液各向同性相的研究完全一致。此外,我们展示了垂直于磁场排列的向列单畴的场致双轴性。我们还在此描述了对向列相施加交流电场的初步实验。发现场振幅和频率都能控制排列方向,并且观察到了垂直排列到平面排列的转变。根据这些数据,使用简单模型来估计向列相的一些物理常数。

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