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针铁矿(α-FeOOH)纳米棒向列型悬浮液的优异磁性能。

Outstanding magnetic properties of nematic suspensions of goethite (alpha-FeOOH) nanorods.

作者信息

Lemaire B J, Davidson P, Ferré J, Jamet J P, Panine P, Dozov I, Jolivet J P

机构信息

Laboratoire de Physique des Solides, UMR CNRS 8502, Bâtiment 510, Université Paris-Sud, 91405 Orsay, France.

出版信息

Phys Rev Lett. 2002 Mar 25;88(12):125507. doi: 10.1103/PhysRevLett.88.125507. Epub 2002 Mar 11.

Abstract

Aqueous suspensions of goethite (alpha-FeOOH) nanorods form a mineral lyotropic nematic phase that aligns in a very low magnetic field (20 mT for samples 20 microm thick). The particles orient along the field direction at intensities smaller than 350 mT, but they reorient perpendicular to the field beyond 350 mT. This outstanding behavior is also observed in the isotropic phase which has a very strong magnetic-field induced birefringence that could be interesting for applications. We interpret these magnetic effects as resulting from a competition between a nanorod remanent magnetic moment and a negative anisotropy of its magnetic susceptibility.

摘要

针铁矿(α-FeOOH)纳米棒的水悬浮液形成一种矿物溶致向列相,该相在非常低的磁场(对于20微米厚的样品为20毫特斯拉)中排列。在强度小于350毫特斯拉时,颗粒沿磁场方向取向,但在超过350毫特斯拉时它们会重新取向至垂直于磁场方向。在各向同性相中也观察到这种显著行为,该相具有很强的磁场诱导双折射,这可能在应用中很有趣。我们将这些磁效应解释为纳米棒剩余磁矩与其磁化率的负各向异性之间竞争的结果。

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