A new, convenient synthesis of the linear phosphazene salt [Cl3P=N=PCl3]Cl: preparation of higher linear homologues [Cl3P=N-(PCl2=N)x=PCl3]Cl (x = 1-3) and the 16-membered macrocycle [NCCl(NPCl2)3]2.
作者信息
Rivard Eric, Lough Alan J, Manners Ian
机构信息
Department of Chemistry, Davenport Laboratories, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.
出版信息
Inorg Chem. 2004 May 3;43(9):2765-7. doi: 10.1021/ic049955z.
PMID:15106959
Abstract
An improved synthetic route to the linear phosphazene salt [Cl3P=N=PCl3]Cl is reported. This species is a useful precursor to higher linear homologues and also to heterocycles such as the 16-membered carbophosphazene macrocycle [NCCl(NPCl2)3]2.
摘要
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