Zhi C Y, Bai X D, Wang E G
State Key Laboratory for Surface Physics and International Center for Quantum Structures, Institute of Physics, Chinese Academy of Sciences, Box 603, Beijing 100080, People's Republic of China.
J Nanosci Nanotechnol. 2004 Jan-Feb;4(1-2):35-51. doi: 10.1166/jnn.2004.018.
A comprehensive understanding of the design, synthesis, characterization, and properties of boron carbonitride nanotubes (BCN) is presented in this review. Distinctive structural and electronic properties are revealed in theoretical studies of the BCN nanotubes and compared with the properties of carbon nanotubes. In the experimental studies, BCN nanotubes have been synthesized by various techniques. For different purposes, controllable growth processes have been used to fabricate BCN nanotubes with novel structures, such as nanojunctions and filled nanotubes. Some interesting phenomena originating from the substitution of B and N atoms, such as the phase segregation, are considered theoretically and experimentally. Mainly the physical properties--field electron emission and photoluminescence--are discussed, which turn out to have potential applications in the industry.
本综述全面介绍了硼碳氮化物纳米管(BCN)的设计、合成、表征及性能。在BCN纳米管的理论研究中揭示了其独特的结构和电子特性,并与碳纳米管的特性进行了比较。在实验研究中,已通过各种技术合成了BCN纳米管。出于不同目的,可控生长过程已被用于制造具有新颖结构的BCN纳米管,如纳米结和填充纳米管。理论和实验上都考虑了一些源于B和N原子取代的有趣现象,如相分离。主要讨论了其物理性质——场电子发射和光致发光——结果表明它们在工业上具有潜在应用。