Jenicek P, Svehla P, Zabranska J, Dohanyos M
Department of Water Technology and Environmental Engineering, Institute of Chemical Technology Prague, Technicka 5, 166 28 Prague 6, Czech Republic.
Water Sci Technol. 2004;49(5-6):73-9.
Nitrogen removal from wastewater with high nitrogen concentration and low COD/N ratio via nitrite is advantageous. The specific character of the sludge liquor enables the application of such a method. The factors affecting process efficiency were studied. From the factors followed pH, NH4+/NH3 and NO2-/HNO2 concentration and distribution seem to be most important, using sequencing batch reactor technology and treating wastewater with high NH4+ concentration (above 1 g/l). The efficient oxidation of N-NH4+ to nitrite was achieved at a minimal nitrate production. Primary sludge was used as an internal source of substrate for the denitritation because of the organic substrate deficiency of the sludge liquor. The denitritation can be controlled by dosing of the primary sludge and can be complete. There are two operational alternatives of sludge liquor pretreatment: without pH control--lower operational costs and N-removal up to 65% and with pH control--higher operational costs and N-removal close to complete.
通过亚硝酸盐从高氮浓度和低COD/N比的废水中去除氮是有利的。污泥液的特殊性质使得这种方法得以应用。研究了影响工艺效率的因素。在使用序批式反应器技术处理高NH4+浓度(高于1 g/l)的废水时,从这些因素来看,pH值、NH4+/NH3和NO2-/HNO2浓度及分布似乎最为重要。在硝酸盐产量最低的情况下实现了N-NH4+向亚硝酸盐的高效氧化。由于污泥液中有机底物不足,初级污泥被用作反硝化的内部底物来源。反硝化可以通过投加初级污泥来控制,并且可以完成。污泥液预处理有两种操作方式:不控制pH值——运行成本较低,氮去除率可达65%;控制pH值——运行成本较高,氮去除接近完全。