芳基硼酸与三甲基氯硅烷 - 硝酸盐的自身硝化反应
ipso-nitration of arylboronic acids with chlorotrimethylsilane-nitrate salts.
作者信息
Prakash G K Surya, Panja Chiradeep, Mathew Thomas, Surampudi Vijayalakshmi, Petasis Nicos A, Olah George A
机构信息
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, California 90089-1661, USA.
出版信息
Org Lett. 2004 Jun 24;6(13):2205-7. doi: 10.1021/ol0493249.
PMID:15200321
Abstract
[reaction: see text] A mixture of nitrate salt and chlorotrimethylsilane is found to be an efficient regioselective nitrating agent for the ipso-nitration of arylboronic acids to produce the corresponding nitroarenes in moderate to excellent yields. High selectivity, simplicity, and convenience are the key features of the reaction.
摘要
[反应：见正文] 发现硝酸盐和三甲基氯硅烷的混合物是一种有效的区域选择性硝化剂，用于芳基硼酸的本位硝化反应，以中等至优异的产率生成相应的硝基芳烃。高选择性、简单性和便利性是该反应的关键特征。
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