利用单电子转移、有机镁或有机锌试剂介导硝基芳烃还原过程的最新进展。
Recent Advances to Mediate Reductive Processes of Nitroarenes Using Single-Electron Transfer, Organomagnesium, or Organozinc Reagents.
作者信息
Zhu Haoran, Driver Tom G
机构信息
Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois, USA, 60607.
出版信息
Synthesis (Stuttg). 2022 Jul;54(14):3142-3161. doi: 10.1055/a-1792-6579. Epub 2022 May 30.
Recent advances in the development of reductive reactions of nitroarenes using organomagnesium-, organozinc-, and single electron transfer reagents is discussed within this review. The review is divided into the following sections: IntroductionOrganomagnesium-mediated reductive reactionsOrganozinc- and zinc-mediated reductive reactionsIodine-catalyzed redox cyclizationsTitanium(III)-mediated reductive cyclizationsSulfur-mediated reductive reactionsAlkoxide-mediated reductive reactions4,4'-Bipyridine-mediated reductive reactionsVisible light-driven reductive amination reactionsElectrochemical reductive reactionsConclusion.
本综述讨论了使用有机镁、有机锌和单电子转移试剂进行硝基芳烃还原反应的最新进展。综述分为以下几个部分：引言；有机镁介导的还原反应；有机锌和锌介导的还原反应；碘催化的氧化还原环化反应；钛（III）介导的还原环化反应；硫介导的还原反应；醇盐介导的还原反应；4,4'-联吡啶介导的还原反应；可见光驱动的还原胺化反应；电化学还原反应；结论。
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