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同步荧光法同时测定空气样品中的对苯二酚和间苯二酚。

Synchronous fluorescence for simultaneous determination of hydroquinone and resorcinol in air samples.

作者信息

Pistonesi M, Cenurión M E, Pereya M, Lista A G, Band B S Fernández

机构信息

FIA Laboratory, Department of Chemistry, Universidad Nacional del Sur, Av. Alem 1253-8000, Bahía Blanca, Argentina.

出版信息

Anal Bioanal Chem. 2004 Mar;378(6):1648-51. doi: 10.1007/s00216-003-2413-0.

Abstract

Several phenolic compounds are present in tobacco smoke. They are formed from the pyrolysis of tobacco during the smoking process and all of them are toxic. Therefore, the determination of these compounds in air samples is important. A rapid, simple, and sensitive method using a synchronous spectrofluorimetry technique was developed to quantify hydroquinone and resorcinol simultaneously. One of the advantages of this method is the simple and rapid sampling technique, which uses water as the absorption solution of the analytes in the air sample. The precision of the method (%RSD) was 1.8% and the detection limits were 0.125 mg m(-3) and 0.292 mg m(-3) for hydroquinone and resorcinol, respectively.

摘要

烟草烟雾中存在多种酚类化合物。它们是在吸烟过程中由烟草热解形成的,且所有这些化合物都有毒。因此,测定空气样品中的这些化合物很重要。已开发出一种使用同步荧光光谱技术的快速、简单且灵敏的方法,可同时定量对苯二酚和间苯二酚。该方法的优点之一是采样技术简单快速,它使用水作为空气样品中分析物的吸收溶液。该方法的精密度(相对标准偏差%)为1.8%,对苯二酚和间苯二酚的检测限分别为0.125 mg m(-3) 和0.292 mg m(-3)。

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