Gong Jiangbin, Rice Stuart A
Department of Chemistry and The James Franck Institute, The University of Chicago, Chicago, Illinois 60637, USA.
J Chem Phys. 2004 Jul 15;121(3):1364-72. doi: 10.1063/1.1764503.
A five-level four-pulse phase-sensitive extended stimulated Raman adiabatic passage scheme is proposed to realize complete control of the population transfer branching ratio between two degenerate target states. The control is achieved via a three-node null eigenstate that can be correlated with an arbitrary superposition of the target states. Our results suggest that complete suppression of the yield of one of two degenerate product states, and therefore absolute selectivity in photochemistry, is achievable and predictable, even without studying the properties of the unwanted product state beforehand.
