Głuch K, Matt-Leubner S, Echt O, Concina B, Scheier P, Märk T D
Institut fur Ionenphysik, Leopold Franzens Universitat, A-6020 Innsbruck, Austria.
J Chem Phys. 2004 Aug 1;121(5):2137-43. doi: 10.1063/1.1768172.
We have measured the kinetic energy released in the unimolecular dissociation of fullerene ions, Cn+ --> C(n-2)+ + C2, for sizes 42 < or = n < or = 90. A three-sector-field mass spectrometer equipped with two electric sectors has been used in order to ensure that contributions from isotopomers of different masses do not distort the experimental kinetic energy release distributions. We apply the concept of microcanonical temperature to derive from these data the dissociation energies of fullerene cations. They are converted to dissociation energies of neutral fullerenes with help of published adiabatic ionization energies. The results are compared with literature values.
