Martínez-Tomé Magdalena, Murcia M Antonia, Frega Natale, Ruggieri Silverio, Jiménez Antonia M, Roses Francisco, Parras Pilar
Department of Food Science, Veterinary Faculty, Campus de Espinardo, University of Murcia, Apartado de Correos 4021, E-30008 Murcia, Spain.
J Agric Food Chem. 2004 Jul 28;52(15):4690-9. doi: 10.1021/jf049621s.
Several oat brans (crunchy oat bran, oat bran alone, and oat breakfast cereal) and wheat brans (wheat bran alone, wheat bran powder, wheat bran with malt flavor, bran breakfast cereal, tablet of bran, and tablet of bran with cellulose) used as dietary fiber supplements by consumers were evaluated as alternative antioxidant sources (i) in the normal human consumer, preventing disease and promoting health, and (ii) in food processing, preserving oxidative alterations. Products containing wheat bran exhibited higher peroxyl radical scavenging effectiveness than those with oat bran. Wheat bran powder was the best hydroxyl radical (OH*) scavenger. In terms of hydrogen peroxide (H2O2) scavenging, wheat bran alone was the most effective, while crunchy oat bran, oat bran alone, and oat breakfast cereal did not scavenge H2O2. The shelf life of fats (obtained by the Rancimat method for butter) increased most in the presence of crunchy oat bran. When the antioxidant activity during 28 days of storage was measured by the linoleic acid assay, all of the oat and wheat bran samples analyzed showed very good antioxidant activities. The Trolox equivalent antioxidant capacity (TEAC) assay was used to provide a ranking order of antioxidant activity. The wheat bran results for TEAC (6 min), in decreasing order, were wheat bran powder > wheat bran with malt flavor > or = wheat bran alone > or = bran breakfast cereal > tablet of bran > tablet of bran with cellulose. The products made with oat bran showed lower TEAC values. In general, avenanthramide showed a higher antioxidant level than each of the following typical cereal components: ferulic acid, gentisic acid, p-hydroxybenzoic acid, protocatechuic acid, syringic acid, vanillic acid, vanillin, and phytic acid.
消费者用作膳食纤维补充剂的几种燕麦麸(脆燕麦麸、纯燕麦麸和燕麦早餐谷物)和小麦麸(纯小麦麸、小麦麸粉、麦芽味小麦麸、麸皮早餐谷物、麸皮片和含纤维素的麸皮片)被评估为替代抗氧化剂来源:(i)在普通人类消费者中,预防疾病和促进健康;(ii)在食品加工中,防止氧化变化。含小麦麸的产品比含燕麦麸的产品表现出更高的过氧自由基清除效果。小麦麸粉是最佳的羟基自由基(OH*)清除剂。在过氧化氢(H2O2)清除方面,纯小麦麸最有效,而脆燕麦麸、纯燕麦麸和燕麦早餐谷物不能清除H2O2。在存在脆燕麦麸的情况下,脂肪的货架期(通过兰奇马特法测定黄油)增加最多。当通过亚油酸测定法测量储存28天期间的抗氧化活性时,所有分析的燕麦和小麦麸样品都显示出非常好的抗氧化活性。采用特洛克斯等效抗氧化能力(TEAC)测定法来提供抗氧化活性的排序。小麦麸的TEAC(6分钟)结果,从高到低依次为:小麦麸粉>麦芽味小麦麸≥纯小麦麸≥麸皮早餐谷物>麸皮片>含纤维素的麸皮片。用燕麦麸制成的产品显示出较低的TEAC值。一般来说,燕麦酰胺的抗氧化水平高于以下典型谷物成分中的每一种:阿魏酸、龙胆酸、对羟基苯甲酸、原儿茶酸、丁香酸、香草酸、香兰素和植酸。