Robles Miguel, López de Haro Mariano, Santos Andrés
Centro de Investigación en Energía, UNAM, Temixco, Morelos 62580, Mexico.
J Chem Phys. 2004 May 15;120(19):9113-22. doi: 10.1063/1.1701840.
Following the work of Leutheusser [Physica A 127, 667 (1984)], the solution to the Percus-Yevick equation for a seven-dimensional hard-sphere fluid is explicitly found. This allows the derivation of the equation of state for the fluid taking both the virial and the compressibility routes. An analysis of the virial coefficients and the determination of the radius of convergence of the virial series are carried out. Molecular-dynamics simulations of the same system are also performed and a comparison between the simulation results for the compressibility factor and theoretical expressions for the same quantity is presented.
继洛伊特瑟尔的工作[《物理学报A》127, 667 (1984)]之后,明确找到了七维硬球流体的珀西 - 耶维克方程的解。这使得能够通过维里和压缩性两种途径推导出该流体的状态方程。对维里系数进行了分析,并确定了维里级数的收敛半径。还对同一系统进行了分子动力学模拟,并给出了压缩因子的模拟结果与该量的理论表达式之间的比较。