Santos Andrés, López de Haro Mariano
Departamento de Física, Universidad de Extremadura, E-06071 Badajoz, Spain.
J Chem Phys. 2009 Jun 7;130(21):214104. doi: 10.1063/1.3147723.
Using the first seven known virial coefficients and forcing it to possess two branch-point singularities, a new equation of state for the hard-sphere fluid is proposed. This equation of state predicts accurate values of the higher virial coefficients, a radius of convergence smaller than the close-packing value, and it is as accurate as the rescaled virial expansion and better than the Pade [3/3] equations of state. Consequences regarding the convergence properties of the virial series and the use of similar equations of state for hard-core fluids in d dimensions are also pointed out.
利用前七个已知的维里系数,并使其具有两个分支点奇点,提出了一种硬球流体的新状态方程。该状态方程预测了更高维里系数的精确值、一个小于紧密堆积值的收敛半径,并且它与重标度维里展开一样精确,且优于帕德[3/3]状态方程。还指出了关于维里级数收敛性质以及在d维中硬核流体使用类似状态方程的相关结果。