Hofmeier Harald, Schubert Ulrich S
Laboratory of Macromolecular Chemistry and Nanoscience, Eindhoven University of Technology and Dutch Polymer Institute, The Netherlands.
Chem Soc Rev. 2004 Jul 30;33(6):373-99. doi: 10.1039/b400653b. Epub 2004 Jul 15.
This critical review describes recent developments in the field of supramolecular chemistry of terpyridine-metal complexes. The synthesis and characteristics of single as well as multiple homo- and heterometallic complexes is discussed. Furthermore, complexes containing fullerenes, biological building blocks, extended aggregates of different architectures as well as rings are presented. A special emphasis is placed upon the properties (e.g. redox properties, luminescence etc.) of functional systems. Potential applications in optical nano-devices, molecular storage units, molecular switches and solar cells are discussed.
这篇批判性综述描述了三联吡啶-金属配合物超分子化学领域的最新进展。讨论了单金属以及多金属同核和异核配合物的合成与特性。此外，还介绍了包含富勒烯、生物构建单元、不同结构的扩展聚集体以及环的配合物。特别强调了功能体系的性质（如氧化还原性质、发光等）。探讨了其在光学纳米器件、分子存储单元、分子开关和太阳能电池中的潜在应用。
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