• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

一些混合碲/硒多硫属阴离子[Te(m)Se(n)]2-的合成与表征

Syntheses and characterization of some mixed Te/Se polychalcogenide anions [Te(m)Se(n)]2-.

作者信息

Sekar Perumal, Ibers James A

机构信息

Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA.

出版信息

Inorg Chem. 2004 Aug 23;43(17):5436-41. doi: 10.1021/ic040026h.

DOI:10.1021/ic040026h
PMID:15310225
Abstract

Several mixed Te/Se polychalcogenide anions Te(m)Se(n) were synthesized at 293 K by reactions between Te(n)(2-)and Se(n)(2-) anions in N,N-dimethylformamide (DMF) in the presence of different-size ammonium or phosphonium cations, in some cases in the presence of metal species. The structures of these anions were determined by single-crystal X-ray diffraction methods. The crystal structures of NEt(4)[Te(3)Se(6)] (1) and NEt(4)[Te(3)Se(7)] (2) consist, respectively, of one-dimensional infinite 1(infinity)[Te(3)Se(6)(2-)] and 1(infinity)[Te(3)Se(7)(2-)] anionic chains separated by NEt(4)(+) cations. In compound 1, each chain comprises Te(3)Se(5) eight-membered rings bridged by Se atoms. The Te(3)Se(5) ring has an "open book" conformation. The NMR spectrum of a DMF solution of NEt(4)[Te(3)Se(6)] crystals at 223 K shows (77)Se resonances at delta = 290, 349, and 771 ppm and a single (125)Te resonance at delta = 944.7 ppm. In compound 2, each chain comprises Te(3)Se(6) five- and six-membered rings bridged by Se atoms. The Te(3)Se(6) ring can be regarded as an inorganic analogue of bicyclononane. The anion of PPh(4)[Te(2)Se(2)] (4) contains a Se-Te-Te-Se chain with the terminal Se atoms trans to one another. The new compounds PPN[TeSe(10)] (3), NMe(4)[TeSe(3)].DMF (5), and NEt(4)[TeSe(3)] (6) contain known anions.

摘要

在293K下，通过碲（n）（2-）和硒（n）（2-）阴离子在N，N-二甲基甲酰胺（DMF）中，在不同尺寸的铵或鏻阳离子存在下，有时在金属物种存在下反应，合成了几种混合的碲/硒多硫属化物阴离子Te（m）Se（n）。通过单晶X射线衍射方法确定了这些阴离子的结构。NEt(4)[Te(3)Se(6)]（1）和NEt(4)[Te(3)Se(7)]（2）的晶体结构分别由一维无限的1（∞）[Te(3)Se(6)(2-)]和1（∞）[Te(3)Se(7)(2-)]阴离子链组成，这些链被NEt(4)(+)阳离子隔开。在化合物1中，每条链包含由硒原子桥连的Te(3)Se(5)八元环。Te(3)Se(5)环具有“打开的书”构象。NEt(4)[Te(3)Se(6)]晶体的DMF溶液在223K下的NMR光谱显示在δ = 290、349和771ppm处有(77)Se共振，在δ = 944.7ppm处有单一的(125)Te共振。在化合物2中，每条链包含由硒原子桥连的Te(3)Se(6)五元环和六元环。Te(3)Se(6)环可被视为双环壬烷的无机类似物。PPh(4)[Te(2)Se(2)]（4）的阴离子包含一个Se-Te-Te-Se链，末端的硒原子彼此反式排列。新化合物PPN[TeSe(10)]（3）、NMe(4)[TeSe(3)].DMF（5）和NEt(4)[TeSe(3)]（6）包含已知的阴离子。

相似文献

1
Syntheses and characterization of some mixed Te/Se polychalcogenide anions [Te(m)Se(n)]2-.一些混合碲/硒多硫属阴离子[Te(m)Se(n)]2-的合成与表征
Inorg Chem. 2004 Aug 23;43(17):5436-41. doi: 10.1021/ic040026h.
2
Synthesis and structural characterization of some selenoruthenates and telluroruthenates.某些硒钌酸盐和碲钌酸盐的合成与结构表征
Inorg Chem. 2005 May 16;44(10):3441-8. doi: 10.1021/ic0483646.
3
Structural and spectroscopic studies of the PCP-bridged heavy chalcogen-centered monoanions [HC(PPh(2)E)(PPh(2))](-) (E = Se, Te) and [HC(PR(2)E)(2)](-) (E = Se, Te, R = Ph; E = Se, R = (i)Pr): homoleptic Group 12 complexes and one-electron oxidation of [HC(PR(2)Se)(2)](-).PCP 桥联重杂中心单阴离子 [HC(PPh(2)E)(PPh(2))](-)（E = Se、Te）和 [HC(PR(2)E)(2)](-)（E = Se、Te、R = Ph；E = Se、R = (i)Pr）的结构和光谱研究：同核 12 族配合物和 [HC(PR(2)Se)(2)](-)的单电子氧化。
Inorg Chem. 2009 Dec 21;48(24):11788-98. doi: 10.1021/ic901878h.
4
Experimental and theoretical investigations of the contact ion pairs formed by reactions of the anions [(EPR2)2N]- (R = (i)Pr, (t)Bu; E = S, Se) with the cations [(TePR2)2N]+ (R = (i)Pr, (t)Bu).实验和理论研究反应[(EPR2)2N]-（R = （i）Pr，（t）Bu；E = S，Se）与阳离子[(TePR2)2N]+（R = （i）Pr，（t）Bu）形成的接触离子对。
Inorg Chem. 2009 Jul 20;48(14):6755-62. doi: 10.1021/ic900703e.
5
Syntheses; 77Se, 203Tl, and 205Tl NMR; and theoretical studies of the Tl2Se6(6-), Tl3Se6(5-), and Tl3Se7(5-) anions and the X-ray crystal structures of [2,2,2-crypt-Na]4[Tl4Se8].en and [2,2,2-crypt-Na]2[Tl2Se4](infinity)1.en.Tl₂Se₆⁶⁻、Tl₃Se₆⁵⁻和Tl₃Se₇⁵⁻阴离子的合成、⁷⁷Se、²⁰³Tl和²⁰⁵Tl核磁共振；理论研究以及[2,2,2-穴醚-Na]₄[Tl₄Se₈]·en和[2,2,2-穴醚-Na]₂[Tl₂Se₄]∞₁·en的X射线晶体结构
Inorg Chem. 2005 Nov 28;44(24):8770-85. doi: 10.1021/ic0510922.
6
Syntheses, structures, and spectroscopic properties of K9Nd[PS4]4, K3Nd[PS4]2, Cs3Nd[PS4]2, and K3Nd3[PS4]4.K9Nd[PS4]4、K3Nd[PS4]2、Cs3Nd[PS4]2和K3Nd3[PS4]4的合成、结构及光谱性质
Inorg Chem. 2008 Sep 1;47(17):7523-34. doi: 10.1021/ic800143x. Epub 2008 Aug 8.
7
Syntheses, crystal structures, and properties of six new lanthanide(III) transition metal tellurium(IV) oxyhalides with three types of structures.六种具有三种结构类型的新型镧系（III）过渡金属碲（IV）卤氧化物的合成、晶体结构及性质
Inorg Chem. 2005 Jul 25;44(15):5328-35. doi: 10.1021/ic050420v.
8
Comparing main group and transition-metal square-planar complexes of the diselenoimidodiphosphinate anion: a solid-state NMR investigation of M[N(iPr2PSe)2]2 (M = Se, Te; Pd, Pt).比较二硒代亚氨基二膦酸根阴离子的主族和过渡金属平面四方配合物：对M[N(iPr₂PSe)₂]₂（M = Se、Te；Pd、Pt）的固态核磁共振研究
Inorg Chem. 2008 Apr 7;47(7):2786-97. doi: 10.1021/ic7019999. Epub 2008 Feb 13.
9
Experimental and theoretical investigations of the redox behavior of the heterodichalcogenido ligands [(EP(i)Pr2)(TeP(i)Pr2)N](-) (E = S, Se): cyclic cations and acyclic dichalcogenide dimers.异二硫属化物配体[(EP(i)Pr2)(TeP(i)Pr2)N](-)（E = S，Se）氧化还原行为的实验与理论研究：环状阳离子和无环二硫属化物二聚体
Inorg Chem. 2008 Nov 17;47(22):10634-43. doi: 10.1021/ic801384c. Epub 2008 Oct 10.
10
Synthesis, spectroscopic, and structural investigation of the cyclic [N(PR2E)2]+ cations (E = Se, Te; R = iPr, Ph): the effect of anion and R-group exchange.环状[N(PR₂E)₂]+阳离子（E = Se，Te；R = iPr，Ph）的合成、光谱及结构研究：阴离子和R基团交换的影响
Inorg Chem. 2006 Dec 25;45(26):10678-87. doi: 10.1021/ic061545i.

引用本文的文献

1
The nature of the chemical bond in linear three-body systems: from i3- to mixed chalcogen/halogen and trichalcogen moieties.线性三原子体系中化学键的本质：从 i3- 到混合硫属/卤化物和三硫属基团。
Bioinorg Chem Appl. 2007;2007:17416. doi: 10.1155/2007/17416.