de Wijn Astrid S, van Beijeren Henk
Institute for Theoretical Physics, Utrecht University, Leuvenlaan 4, 3584 CE, Utrecht, The Netherlands.
Phys Rev E Stat Nonlin Soft Matter Phys. 2004;70(1 Pt 2):016207. doi: 10.1103/PhysRevE.70.016207. Epub 2004 Jul 15.
In the study of chaotic behavior, Lyapunov exponents play an important part. In this paper, we demonstrate how the Lyapunov exponents close to zero of a system of many hard spheres can be described as Goldstone modes, by using a Boltzmann type of approach. At low densities, the correct form is found for the wave number dependence of the exponents as well as for the corresponding eigenvectors in tangent space. The predicted values for the Lyapunov exponents belonging to the transverse mode are within a few percent of the values found in recent simulations, the propagation velocity for the longitudinal mode is within 1%, but the value for the Lyapunov exponent belonging to the longitudinal mode deviates from the simulations by 30%. For higher densities, the predicted values deviate more from the values calculated in the simulations. These deviations may be due to contributions from ring collisions and similar terms, which, even at low densities, can contribute to the leading order.