Seo G T, Ahan H I, Kim J T, Lee Y J, Kim I S
Department Environmental Engineering Changwon national University, Sarim-Dong 9, Changwon, Gyeongnam 641-773, South Korea.
Water Sci Technol. 2004;50(2):173-8.
This study focuses on the practical application of high concentration powdered activated carbon coupled membrane bio-reactor to domestic wastewater reclamation. The study was conducted in three parts, such as analysis of secondary domestic wastewater effluent, design and operation parameter evaluation and reclaimed water quality estimation for stream restoration. The organic concentration was 25.2-80.2 mgCOD(Cr)/L for the effluent of three domestic wastewater treatment plants. Around 50-75% of the COD was low molecular substances less than 1,000 which were quite biodegradable. The sawdust PAC was estimated to be proper adsorbent for the organics in the secondary effluents. Its Freundlich constant, K value was 5.847 and 1/n, 0.36. Using a system consists of single reactor with high concentration PAC (80 g/L) and submerged hollow fiber MF membrane module with nominal pore size of 0.1 microm, design and operation parameters were obtained, such as HRT of the bioreactor (2.5 hr), PAC concentration (80 g/L), the initial flux (less than 0.5 m/day) and intermittent suction cycle (12 min. suction and 3 min. idling). Organic removal by the system was high enough to produce reclaimed water for urban stream restoration The effluent organic concentration was at the level of 2 mg/L in terms of TOC (around 5 mg/L as COD(Cr)). Substances with molecular weight cut off < 1,000 were removed mostly by adsorption and biodegradation. Those above 1,000 were rejected at PAC cake layer on the membrane and gradually degraded by microorganisms during extended contact.
本研究聚焦于高浓度粉末活性炭耦合膜生物反应器在生活污水回用中的实际应用。该研究分为三个部分进行,即生活污水二级出水分析、设计与运行参数评估以及用于河流修复的再生水水质估算。三个生活污水处理厂的出水有机浓度为25.2 - 80.2mgCOD(Cr)/L。约50 - 75%的化学需氧量是分子量小于1000的低分子物质,这些物质具有较高的生物降解性。锯末粉末活性炭被认为是二级出水中有机物的合适吸附剂。其弗罗因德利希常数K值为5.847,1/n为0.36。使用由一个装有高浓度粉末活性炭(80g/L)的单反应器和标称孔径为0.1微米的浸没式中空纤维微滤膜组件组成的系统,获得了生物反应器的水力停留时间(2.5小时)、粉末活性炭浓度(80g/L)、初始通量(小于0.5m/天)和间歇抽吸周期(抽吸12分钟,闲置3分钟)等设计和运行参数。该系统对有机物的去除效果良好,足以生产用于城市河流修复的再生水。出水有机浓度以总有机碳计为2mg/L(以COD(Cr)计约为5mg/L)。分子量截留值<1000的物质主要通过吸附和生物降解去除。分子量大于1000的物质在膜上的粉末活性炭滤饼层被截留,并在延长接触过程中被微生物逐渐降解。