Lin D J, Chern Lin J H, Ju C P
Department of Materials Science and Engineering, National Cheng-Kung University, Tainan, Taiwan, ROC.
J Mater Sci Mater Med. 2003 Jan;14(1):1-7. doi: 10.1023/a:1021559700915.
The present work is a study of a series of Ti-7.5Mo-xCr alloys with the focus on the effect of chromium content on the structure and mechanical properties of the alloys. Experimental results show that low hardness, strength and modulus binary Ti-7.5Mo alloy is comprised primarily of fine, acicular martensitic alpha' phase. When 1 wt % Cr is added, a small amount of beta phase is retained. With 2 wt % or more chromium added, the entire alloy becomes equi-axed beta phase with bcc crystal structure. The average beta grain size decreases with Cr content. When the alloy contains about 2-4 wt % Cr, a metastable omega phase is present. In Ti-7.5Mo-2Cr alloy appears the highest omega intensity accompanied with high microhardness, bending strength and modulus. The omega-induced embrittling effect is most profound in Ti-7.5Mo-2Cr alloy that exhibits a terrace type fracture surface covered with numerous micron-sized dimples. The alloys with higher Cr contents show normal ductile type fractography with much larger deformation dimples. The present results indicate that Ti-7.5Mo-(4-6)Cr alloys seem to be potential candidates for implant application.
本研究工作是对一系列Ti-7.5Mo-xCr合金进行研究,重点关注铬含量对合金组织和力学性能的影响。实验结果表明,低硬度、强度和模量的二元Ti-7.5Mo合金主要由细小的针状马氏体α'相组成。当添加1 wt%的Cr时,会保留少量的β相。当添加2 wt%或更多的铬时,整个合金变为具有体心立方晶体结构的等轴β相。平均β晶粒尺寸随Cr含量的增加而减小。当合金含有约2-4 wt%的Cr时,会出现亚稳ω相。在Ti-7.5Mo-2Cr合金中,ω相的强度最高,同时具有较高的显微硬度、抗弯强度和模量。ω相引起的脆化效应在Ti-7.5Mo-2Cr合金中最为显著,其断口表面呈现出梯田状,覆盖着许多微米级的凹坑。含铬量较高的合金呈现出正常的韧性断口形貌,具有更大的变形凹坑。目前的结果表明,Ti-7.5Mo-(4-6)Cr合金似乎是植入应用的潜在候选材料。