Cheng W W, Ju C P, Lin J H Chern
Department of Materials Science and Engineering, National Cheng-Kung University, Tainan, Taiwan.
J Oral Rehabil. 2007 Jul;34(7):528-40. doi: 10.1111/j.1365-2842.2003.01151.x.
This report is a study of structure, castability, mechanical properties as well as corrosion behaviour of titanium doped with up to 5 weight percentage (wt%) of a series of alloy elements, including Ta, Mo, Nb, Hf, Zr, Sn, Bi and Ag. The results indicate that, with addition of 1 wt% alloy element, Bi and Mo were most effective in enhancing the castability of titanium. With more alloy elements added, the castability values of most alloys more or less decreased. Except Ti-Mo system, all Ti alloys with a fine acicular morphology had the same crystal structure (hcp) as that of c.p. Ti with a typical lath type morphology. When 3 wt% or more Mo was added, a finer orthorhombic alpha'' phase was formed. The microhardness and bending strength values of Ti alloys were all higher than those of c.p. Ti. Among all alloys, Ti-Mo system exhibited the highest hardness and strength level. For a certain alloy, the bending strength did not necessarily increase with its alloy content. Except Ti-5Zr and Ti-Mo alloys, the bending moduli of most alloy systems were not much different from that of c.p. Ti. All alloys showed an excellent resistance to corrosion in Hanks' solution at 37 degrees C.
本报告是对掺杂了高达5重量百分比(wt%)一系列合金元素(包括钽(Ta)、钼(Mo)、铌(Nb)、铪(Hf)、锆(Zr)、锡(Sn)、铋(Bi)和银(Ag))的钛的结构、铸造性能、力学性能以及腐蚀行为的研究。结果表明,添加1 wt%合金元素时,铋和钼对提高钛的铸造性能最有效。随着添加更多合金元素,大多数合金的铸造性能值或多或少有所下降。除了Ti-Mo体系外,所有具有细小针状形态的钛合金都具有与具有典型板条形态的工业纯钛相同的晶体结构(hcp)。当添加3 wt%或更多钼时,会形成更细小的正交α''相。钛合金的显微硬度和弯曲强度值均高于工业纯钛。在所有合金中,Ti-Mo体系表现出最高的硬度和强度水平。对于某一合金,其弯曲强度不一定随合金含量增加而提高。除了Ti-5Zr和Ti-Mo合金外,大多数合金体系的弯曲模量与工业纯钛的弯曲模量相差不大。所有合金在37℃的汉克斯溶液中均表现出优异的耐腐蚀性。