吲哚酚 N(4)-甲基硫代半卡巴腙铜(II)配合物的光谱表征
Spectroscopic characterization of copper(II) complexes of indoxyl N(4)-methyl thiosemicarbazone.
作者信息
Chandra Sulekh, Kumar Umendra
机构信息
Department of Chemistry, Zakir Husain College, University of Delhi, J.L. Nehru Marg, New Delhi 110002, India.
出版信息
Spectrochim Acta A Mol Biomol Spectrosc. 2004 Oct;60(12):2825-9. doi: 10.1016/j.saa.2004.01.020.
New copper(II) complexes of indoxyl thiosemicarbazone (ITSC) of general composition CuL2X2 (where L: ITSC; X: Cl-, NO3-, ClO4-, NCS-) have been synthesized and characterized by elemental analysis, molar conductance, magnetic susceptibility measurements and spectral (electronic, IR, EPR, 1H NMR, Mass) studies. Cyclic voltammetry measurements show quasi-reversible Cu2+/Cu1+ couple. Various physico-chemical techniques suggest a tetragonal structure for these copper(II) complexes.
已合成了通式为CuL2X2（其中L：吲哚硫代半卡巴腙；X：Cl-、NO3-、ClO4-、NCS-）的新型铜（II）吲哚硫代半卡巴腙配合物（ITSC），并通过元素分析、摩尔电导率、磁化率测量和光谱（电子、红外、电子顺磁共振、1H核磁共振、质谱）研究对其进行了表征。循环伏安法测量显示了准可逆的Cu2+/Cu1+电对。各种物理化学技术表明这些铜（II）配合物具有四方结构。
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