Reduction of 1,4-dichlorobut-2-yne by titanocene to a 1,2,3-butatriene. Formation of a 1-titanacyclopent-3-yne and a 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene.
作者信息
Burlakov Vladimir V, Arndt Perdita, Baumann Wolfgang, Spannenberg Anke, Rosenthal Uwe, Parameswaran Pattiyil, Jemmis Eluvathingal D
机构信息
Leibniz-Institut fur Organische Katalyse an der Universitat Rostock e.V., Buchbinderstr. 5-6, D-18055 Rostock, Germany.
出版信息
Chem Commun (Camb). 2004 Sep 21(18):2074-5. doi: 10.1039/b406494a. Epub 2004 Aug 11.
DOI:10.1039/b406494a
PMID:15367981
Abstract
The 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene (bis-titanocene-mu-(Z)-1,2,3-butatriene complex)3 is formed starting from [Cp2Ti(eta2-Me3SiC2SiMe3)] by in situ generated titanocene and 1,4-dichlorobut-2-yne via the 1-titanacyclobut-3-yne (2).
摘要
Zotero 插件