含锑配体的多核二茂钛配合物：[(Cp2Ti)2(SbR2)2]（R = 乙基）、[(Cp2Ti)3(SbR)3Sb] [R = 2-(二甲基氨基甲基)苯] 和 [(Cp2Ti)5(SbR)2Sb7]（R = 三甲基硅基甲基）

Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R=Et), [(Cp2Ti)3(SbR)3Sb] [R=2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R=Me3SiCH2).

作者信息

Breunig Hans J, Lork Enno, Moldovan Ovidiu, Raţ Ciprian I, Rosenthal Uwe, Silvestru Cristian

机构信息

Institut für Anorganische und Physikalische Chemie, Universität Bremen, Postfach 330 440, D-28334, Bremen, Germany.

出版信息

Dalton Trans. 2009 Jul 14(26):5065-7. doi: 10.1039/b904846d. Epub 2009 May 13.

DOI:10.1039/b904846d

PMID:19562162

Abstract

The formation and crystal structure of [(Cp2Ti)2(SbR2)2] (1, R=Et), [(Cp2Ti)3(SbR)3Sb] [2, R=2-(Me2NCH2)C6H4], and [(Cp2Ti)5(SbR)2Sb7] (3, R=Me3SiCH2) is reported.

摘要

报道了[(Cp2Ti)2(SbR2)2]（1，R = 乙基）、[(Cp2Ti)3(SbR)3Sb] [2，R = 2-(Me2NCH2)C6H4]和[(Cp2Ti)5(SbR)2Sb7]（3，R = Me3SiCH2）的形成及其晶体结构。

相似文献

Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R=Et), [(Cp2Ti)3(SbR)3Sb] [R=2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R=Me3SiCH2).

Dalton Trans. 2009 Jul 14(26):5065-7. doi: 10.1039/b904846d. Epub 2009 May 13.

New chiral organoantimony(III) compounds containing intramolecular N --> Sb interactions--solution behaviour and solid state structures.

Dalton Trans. 2010 Jul 28;39(28):6410-8. doi: 10.1039/c003318a. Epub 2010 May 10.

Titanocene(III) complexes with 2-phosphinoaryloxide ligands for the catalytic dehydrogenation of dimethylamine borane.

Dalton Trans. 2015 Jul 21;44(27):12103-11. doi: 10.1039/c5dt00275c.

Hypervalent organobismuth(iii) carbonate, chalcogenides and halides with the pendant arm ligands 2-(Me2NCH2)C6H4 and 2,6-(Me2NCH2)2C6H3.

Dalton Trans. 2008 Apr 14(14):1831-42. doi: 10.1039/b717127g. Epub 2008 Feb 27.

Versatile {CpTi} Grafted Hetero-Polyoxotungstate Clusters: Synthesis, Crystal Structure, and Photocurrent Properties.

Inorg Chem. 2020 Jan 21;59(2):1125-1136. doi: 10.1021/acs.inorgchem.9b02743. Epub 2020 Jan 3.

On the coordination non-innocence of antimony in nickel(ii) complexes of the tetradentate (o-(PhP)CH)Sb ligand.

Dalton Trans. 2017 May 2;46(17):5598-5604. doi: 10.1039/c6dt04817j.

Isomers of a dibismuthane, R2Bi-BiR2 [R = 2,6-(Me2NCH2)2C6H3], and unusual reactions with oxygen: formation of [R2Bi]2(O2) and R'R' 'Bi [R' = 2-(Me2NCH2)-6-{Me2N(O)CH2}C6H3; R' ' = 2-(Me2NCH2)-6-{O(O)C}C6H3].

Inorg Chem. 2006 Mar 6;45(5):2341-6. doi: 10.1021/ic052160n.

Titanocene(II)-promoted, one-pot, three-component coupling of thioacetals, alkynyl sulfones, and carbonyl compounds: highly stereoselective formation of tert-homopropargyl alcohols.

Org Lett. 2007 Jul 19;9(15):2875-8. doi: 10.1021/ol071077w. Epub 2007 Jun 20.

Reduction of 1,4-dichlorobut-2-yne by titanocene to a 1,2,3-butatriene. Formation of a 1-titanacyclopent-3-yne and a 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene.

Chem Commun (Camb). 2004 Sep 21(18):2074-5. doi: 10.1039/b406494a. Epub 2004 Aug 11.

[Cp2Ti(III)(NCy)2C-Ti(III)Cp2]: a transient titanocene carbene complex?

Angew Chem Int Ed Engl. 2010 Nov 22;49(48):9282-5. doi: 10.1002/anie.201004145.

引用本文的文献

Antimony-ligated dysprosium single-molecule magnets as catalysts for stibine dehydrocoupling.

Chem Sci. 2017 Mar 1;8(3):2073-2080. doi: 10.1039/c6sc04465d. Epub 2016 Nov 21.

Metalated Oligosilanylstibines.

Organometallics. 2015 Apr 27;34(8):1431-1439. doi: 10.1021/om501297h. Epub 2015 Apr 10.

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型，支持多种主流文档格式。

立即体验

含锑配体的多核二茂钛配合物：[(Cp2Ti)2(SbR2)2]（R = 乙基）、[(Cp2Ti)3(SbR)3Sb] [R = 2-(二甲基氨基甲基)苯] 和 [(Cp2Ti)5(SbR)2Sb7]（R = 三甲基硅基甲基）

Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R=Et), [(Cp2Ti)3(SbR)3Sb] [R=2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R=Me3SiCH2).

作者信息

机构信息

出版信息

相似文献

引用本文的文献

文献AI研究员

用中文搜PubMed

文档翻译

Suppr 超能文献

含锑配体的多核二茂钛配合物：[(Cp2Ti)2(SbR2)2]（R = 乙基）、[(Cp2Ti)3(SbR)3Sb] [R = 2-(二甲基氨基甲基)苯] 和 [(Cp2Ti)5(SbR)2Sb7]（R = 三甲基硅基甲基）

Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R=Et), [(Cp2Ti)3(SbR)3Sb] [R=2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R=Me3SiCH2).

作者信息

机构信息

出版信息

相似文献

引用本文的文献