Lebiedz Dirk, Brandt-Pollmann Ulrich
Interdisciplinary Center for Scientific Computing, Im Neuenheimer Feld 368, D-69120 Heidelberg, Germany.
Chaos. 2004 Sep;14(3):611-6. doi: 10.1063/1.1776431.
Specific external control of chemical reaction systems and both dynamic control and signal processing as central functions in biochemical reaction systems are important issues of modern nonlinear science. For example nonlinear input-output behavior and its regulation are crucial for the maintainance of the life process that requires extensive communication between cells and their environment. An important question is how the dynamical behavior of biochemical systems is controlled and how they process information transmitted by incoming signals. But also from a general point of view external forcing of complex chemical reaction processes is important in many application areas ranging from chemical engineering to biomedicine. In order to study such control issues numerically, here, we choose a well characterized chemical system, the CO oxidation on Pt(110), which is interesting per se as an externally forced chemical oscillator model. We show numerically that tuning of temporal self-organization by input signals in this simple nonlinear chemical reaction exhibiting oscillatory behavior can in principle be exploited for both specific external control of dynamical system behavior and processing of complex information.
化学反应系统的特定外部控制以及动态控制和信号处理作为生化反应系统的核心功能,是现代非线性科学的重要问题。例如,非线性输入输出行为及其调节对于维持生命过程至关重要,而生命过程需要细胞与其环境之间进行广泛的通信。一个重要的问题是生化系统的动力学行为是如何被控制的,以及它们如何处理传入信号所传递的信息。但从一般观点来看,复杂化学反应过程的外部强迫在从化学工程到生物医学的许多应用领域中也很重要。为了从数值上研究此类控制问题,在此我们选择一个特征明确的化学系统,即Pt(110)上的CO氧化反应,它本身作为一个外部强迫化学振荡器模型就很有趣。我们通过数值计算表明,在这个表现出振荡行为的简单非线性化学反应中,利用输入信号对时间自组织进行调节,原则上可用于动态系统行为的特定外部控制和复杂信息的处理。