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一种使用涂覆纤维素纸评估可生物降解塑料的新方法。

A new method for the evaluation of biodegradable plastic using coated cellulose paper.

作者信息

Lim Hyun-A, Raku Takao, Tokiwa Yutaka

机构信息

Institute of Agricultural Science & Technology, Chonbuk National University, Jeonju, 561-756, Korea.

出版信息

Macromol Biosci. 2004 Sep 16;4(9):875-81. doi: 10.1002/mabi.200400053.

Abstract

A highly sensitive analytical method for evaluation of poly(L-lactide) (PLA), poly(epsilon-caprolactone) (PCL), poly(beta-hydroxybutyrate) (PHB), and poly(butylene succinate) (PBS) degradability was developed using coated cellulose paper, prepared by penetration and adhesion of these plastics into/onto the cellulose paper. Enzymatic degradability of the obtained plastic coated papers was evaluated using various commercial proteases and lipases. PLA coated paper was highly susceptible to subtilisin and mammalian enzymes, alpha-chymotrypsin, elastase and trypsin. To our knowledge, this is the first report on the degradation of PLA coated paper using subtilisin and mammalian enzymes. Almost all lipase preparations degraded PCL and PHB coated papers but not PBS coated paper. The biodegradability of plastic coated paper was greater than that of plastic powder. The penetration of plastic into cellulose paper by coating improved the plastic degradability, and can be regulated easily.

摘要

通过将这些塑料渗透并粘附到纤维素纸上制备涂层纤维素纸,开发了一种用于评估聚(L-丙交酯)(PLA)、聚(ε-己内酯)(PCL)、聚(β-羟基丁酸酯)(PHB)和聚(丁二酸丁二醇酯)(PBS)降解性的高灵敏度分析方法。使用各种商业蛋白酶和脂肪酶评估所得塑料涂层纸的酶促降解性。PLA涂层纸对枯草杆菌蛋白酶和哺乳动物酶(α-胰凝乳蛋白酶、弹性蛋白酶和胰蛋白酶)高度敏感。据我们所知,这是关于使用枯草杆菌蛋白酶和哺乳动物酶降解PLA涂层纸的首次报道。几乎所有脂肪酶制剂都能降解PCL和PHB涂层纸,但不能降解PBS涂层纸。塑料涂层纸的生物降解性大于塑料粉末。通过涂层使塑料渗透到纤维素纸中提高了塑料的降解性,并且易于调节。

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