通过黄原酸酯自由基加成-环化序列生成的α-四氢萘酮合成取代萘。
Synthesis of substituted naphthalenes from alpha-tetralones generated by a xanthate radical addition-cyclisation sequence.
作者信息
Cordero-Vargas Alejandro, Perez-Martin Ines, Quiclet-Sire Beatrice, Zard Samir Z
机构信息
Laboratoire de Synthèse Organique associé au CNRSM Palaiseau, France.
出版信息
Org Biomol Chem. 2004 Oct 21;2(20):3018-25. doi: 10.1039/B411158C. Epub 2004 Sep 27.
DOI:10.1039/B411158C
PMID:15480467
Abstract
A simple, highly efficient and cheap synthesis of substituted naphthalenes is reported. These aromatic compounds can be easily prepared in acidic or basic conditions from [small alpha]-tetralones, obtained by a xanthate-mediated addition-cyclisation sequence.
摘要
报道了一种简单、高效且廉价的取代萘的合成方法。这些芳香化合物可在酸性或碱性条件下，由通过黄原酸酯介导的加成环化序列得到的[小α]-四氢萘酮轻松制备。
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