Feng K, Yu B Y, Wang X L, Ge D M, Wang X Z, Wong M H, Cao Z H
Agricultural College of Yangzhou University, Yangzhou 225009, PR China.
Environ Geochem Health. 2004 Jun-Sep;26(2-3):253-8. doi: 10.1023/b:egah.0000039588.10092.37.
This paper reports a study of the distribution of organo-chlorine pesticides (DDT and HCH) between rice plants and the soil system by spraying before the heading stage at four different dosage levels--control, normal dosage (15 kg ha(-1) of 6% HCH and 7.5 kg ha(-1) of 25% DDT), double dosage and four times dosage. Soil and plant samples were taken respectively at the 1st h, 3rd, 10th, 20th, and 40th day after spraying and at the harvest time. The results indicate that less than 5% of HCH and 15% of DDT were absorbed by the surface of rice leaves for normal dosage. Most of both pesticides moved into the soil in solution after spraying. Compared with DDT, HCH was degraded and run off more easily. HCH residues in the surface soil layer (1-3 cm) were already below 6.4 microg kg(-1) at the mature stage, lower than Chinese Environmental Quality Standard for Agricultural Soils: HCH < 0.05 mg kg(-1). However DDT residues in the surface soil layer remained 172 microg kg(-1), higher than the national standard: DDT < 0.05 mg kg(-1). According to the test f OCP residues in rice seeds, it can be concluded that the OCP sprayed onto the surface of rice leaves can move into rice plants and accumulate in the seeds at the mature stage. HCH residues in rice seeds of the double and four times dosage treatments, and DDT residues in all treatments, exceeded the Chinese National Food Standard (HCH < 0.10 mg kg(-1), DDT < 0.20 mg kg(-1)).
本文报道了一项关于在抽穗期前以四种不同剂量水平(对照、正常剂量(6%六六六15 kg·ha⁻¹和25%滴滴涕7.5 kg·ha⁻¹)、双倍剂量和四倍剂量)进行喷洒后,有机氯农药(滴滴涕和六六六)在水稻植株与土壤系统之间分布的研究。在喷洒后的第1小时、第3天、第10天、第20天、第40天以及收获期分别采集土壤和植物样本。结果表明,对于正常剂量,六六六不到5%、滴滴涕15%被水稻叶片表面吸收。两种农药在喷洒后大多以溶液形式进入土壤。与滴滴涕相比,六六六更易降解和流失。在成熟期,表层土壤(1 - 3厘米)中六六六残留量已低于6.4微克·千克⁻¹,低于中国《土壤环境质量标准 农用地土壤污染风险管控标准(试行)》:六六六<0.05毫克·千克⁻¹。然而,表层土壤中滴滴涕残留量仍为172微克·千克⁻¹,高于国家标准:滴滴涕<0.05毫克·千克⁻¹。根据水稻种子中有机氯农药残留量的检测结果可以得出,喷洒在水稻叶片表面的有机氯农药能够进入水稻植株并在成熟期在种子中积累。双倍剂量和四倍剂量处理的水稻种子中六六六残留量以及所有处理的水稻种子中滴滴涕残留量均超过中国国家食品标准(六六六<0.10毫克·千克⁻¹,滴滴涕<0.20毫克·千克⁻¹)。