Kioseoglou George, Hanbicki Aubrey T, Sullivan James M, van 't Erve Olaf M J, Li Connie H, Erwin Steven C, Mallory Robert, Yasar Mesut, Petrou Athos, Jonker Berend T
Materials Science and Technology Division, Naval Research Laboratory, 4555 Overlook Avenue SW, Washington, DC 20375, USA.
Nat Mater. 2004 Nov;3(11):799-803. doi: 10.1038/nmat1239. Epub 2004 Oct 17.
The use of carrier spin in semiconductors is a promising route towards new device functionality and performance. Ferromagnetic semiconductors (FMSs) are promising materials in this effort. An n-type FMS that can be epitaxially grown on a common device substrate is especially attractive. Here, we report electrical injection of spin-polarized electrons from an n-type FMS, CdCr(2)Se(4), into an AlGaAs/GaAs-based light-emitting diode structure. An analysis of the electroluminescence polarization based on quantum selection rules provides a direct measure of the sign and magnitude of the injected electron spin polarization. The sign reflects minority rather than majority spin injection, consistent with our density-functional-theory calculations of the CdCr(2)Se(4) conduction-band edge. This approach confirms the exchange-split band structure and spin-polarized carrier population of an FMS, and demonstrates a litmus test for these FMS hallmarks that discriminates against spurious contributions from magnetic precipitates.
在半导体中利用载流子自旋是实现新器件功能和性能的一条有前途的途径。铁磁半导体(FMS)是这项工作中很有前景的材料。一种可以在常见器件衬底上外延生长的n型FMS尤其具有吸引力。在此,我们报告了从n型FMS CdCr₂Se₄向基于AlGaAs/GaAs的发光二极管结构电注入自旋极化电子。基于量子选择规则对电致发光极化的分析提供了对注入电子自旋极化的符号和大小的直接测量。该符号反映的是少数而非多数自旋注入,这与我们对CdCr₂Se₄导带边缘的密度泛函理论计算一致。这种方法证实了FMS的交换分裂能带结构和自旋极化载流子分布,并展示了一种针对这些FMS特征的石蕊测试,可区分来自磁性沉淀物的虚假贡献。