Jing Guo-hua, Li Wei, Shi Yao, Ma Bi-yao, Tan Tian-en
Institute of Environmental Engineering, Zhejiang University, Hangzhou 310027, China.
Huan Jing Ke Xue. 2004 Jul;25(4):163-6.
Metal chelate absorption is deemed as a promising method of NO removal in FGD system, but the difficulty in the regeneration of the absorption solution hinders its further development. An original method with microbial reduction is proposed in this paper. With the adding of Psudomonas sp. DN-1, which was newly isolated from wastewater treatment plant, FeII (EDTA) NO will be reduced to the environmentally benign gaseous product of N2, and thus FeII (EDTA) was regenerated simultaneously. The effects of the types and amount of carbon source, FeII (EDTA) NO concentration, pH, temperature and the biomass inoculation on bio-reduction efficiency were investigated. The results showed that the microorganism exhibited good performance on bio-reduction of FeII (EDTA) NO with the carbon sources of glucose. 250 mg x L(-1) glucose was enough for microorganism to reduce 6.50 mmol x L(-1) FeII (EDTA) NO completely. The rate of FeII (EDTA) NO reduction did not increase with adding a larger amount of carbon source. The bio-reduction could be achieved efficiently among the temperature range of 40 - 45 degrees C and a pH range of 6.9 - 7.2. The bio-reduction rate increased with the increasing of biomass inoculation. When FeII (EDTA) NO concentration is less than 11.8 mmol x L(-1), the reduction rate increased as the concentration increases, while the concentration is over 11.8 mmol x L(-1), the reduction rate keeps constant.
金属螯合物吸收法被认为是一种很有前景的烟气脱硫系统中脱除一氧化氮的方法,但吸收液再生困难阻碍了其进一步发展。本文提出了一种微生物还原的新方法。通过添加从污水处理厂新分离出的假单胞菌属DN - 1,FeII(EDTA)NO将被还原为环境友好的气态产物N2,同时FeII(EDTA)得以再生。研究了碳源种类和用量、FeII(EDTA)NO浓度、pH值、温度和生物量接种量对生物还原效率的影响。结果表明,该微生物对以葡萄糖为碳源的FeII(EDTA)NO生物还原表现出良好性能。250 mg·L(-1)的葡萄糖足以使微生物完全还原6.50 mmol·L(-1)的FeII(EDTA)NO。添加大量碳源时,FeII(EDTA)NO的还原速率并未增加。在40 - 45℃的温度范围和6.9 - 7.2的pH范围内可有效实现生物还原。生物还原速率随生物量接种量的增加而提高。当FeII(EDTA)NO浓度小于11.8 mmol·L(-1)时,还原速率随浓度增加而增大,而当浓度超过11.8 mmol·L(-1)时,还原速率保持恒定。