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catena-Poly[[bis(pentane-2,4-dionato-kappa2O,O')cobalt(II)]-mu-4,4'-methylenedianiline-kappa2N:N'].

作者信息

Zhi Xin-Lei, Zhang Wen-Hua, Zhang Yong, Lang Jian-Ping

机构信息

Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou Uinversity, Suzhou 215006, Jiangsu, People's Republic of China.

出版信息

Acta Crystallogr C. 2004 Nov;60(Pt 11):m554-6. doi: 10.1107/S0108270104022073. Epub 2004 Oct 22.

DOI:10.1107/S0108270104022073
PMID:15528801
Abstract

In the title compound, Co(C(5)H(7)O(2))(2)(C(13)H(14)N(2)) or Co(acac)(2)(dadpm), where acac is acetylacetonate and dadpm is 4,4'-methylenedianiline, the Co atom is on a centre of symmetry and is octahedrally coordinated by four O atoms from two acac anions and by two N atoms from two dadpm ligands. Each dadpm ligand, which has a twofold axis passing through its methylene C atom, bridges two Co atoms to form a spiral polymeric chain. Neighbouring chains connect via hydrogen bonds to form a two-dimensional network.

摘要

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