Kontturi Mervi, Peräniemi Sirpa, Vepsäläinen Jouko J, Ahlgrén Markku
University of Joensuu, Department of Chemistry, PO Box 111, FIN-80101 Joensuu, Finland.
Acta Crystallogr C. 2004 Nov;60(Pt 11):m592-4. doi: 10.1107/S0108270104023704. Epub 2004 Oct 31.
The title compound, [Ba(3)(CHCl(2)O(6)P(2))(2)(H(2)O)(4)].H(2)O or [Ba(3)(Cl(2)CP(2)O(6)H)(H(2)O)(4)].H(2)O, is two-dimensional. The asymmetric unit contains three independent Ba(2+) atoms, two chelating and bridging Cl(2)CP(2)O(6)H(3-) ligands and four aqua ligands, connected in layers parallel to the (100) plane. There are pores between the layers in the direction of the b axis filled with lattice water molecules.
标题化合物[[Ba₃(CHCl₂O₆P₂)₂(H₂O)₄]·H₂O]ₙ或[[Ba₃(Cl₂CP₂O₆H)(H₂O)₄]·H₂O]ₙ为二维结构。不对称单元包含三个独立的Ba²⁺原子、两个螯合且桥连的Cl₂CP₂O₆H³⁻配体和四个水合配体，它们在平行于(100)平面的层中相连。沿b轴方向的层间存在孔隙，其中填充有晶格水分子。
