Oliveira Geiza E, Holanda José Nilson F
Advanced Materials Laboratory, Northern Fluminense State University, Campos dos Goytacazes-RJ, Brazil.
Waste Manag Res. 2004 Oct;22(5):358-63. doi: 10.1177/0734242X04047209.
The present study focuses on the use of solid waste generated by the steel works in Brazil for manufacturing clay-based structural products. The waste sample was characterized regarding chemical composition, X-ray diffraction, particle size, morphology, specific surface and plastic properties. The waste was added in gradual proportions to a kaolinitic clay from zero up to 3 wt.%. Ceramic bodies were formed by vacuum extrusion and fired at 950 degrees C. The physical-mechanical properties (linear shrinkage, water absorption, apparent density and flexural strength) of the resulting clay/solid waste mixtures were determined. In addition, leaching tests were performed according Brazilian Standards as well as a preliminary analysis of gases evolved during the thermal process. It was found that the solid waste is formed by irregular particles, ranging in size from 1 to 500 microm. The test results indicate that solid wastes generated by steel works can be used as filler in construction materials, thereby increasing reuse in an environmentally safe manner.
本研究聚焦于巴西钢铁厂产生的固体废物用于制造粘土基结构产品。对废物样本进行了化学成分、X射线衍射、粒度、形态、比表面积和塑性性能等方面的表征。将废物按逐渐增加的比例添加到高岭土中,添加量从零到3重量%。通过真空挤压成型陶瓷坯体,并在950摄氏度下烧制。测定了所得粘土/固体废物混合物的物理力学性能(线性收缩率、吸水率、表观密度和抗弯强度)。此外,根据巴西标准进行了浸出试验,并对热过程中释放的气体进行了初步分析。结果发现,固体废物由不规则颗粒组成,粒径范围为1至500微米。试验结果表明,钢铁厂产生的固体废物可作为建筑材料中的填料,从而以环境安全的方式提高再利用率。