Manipulation of the stereochemical outcome and product distribution in the Henry reaction using CO2 pressure.
作者信息
Parratt Andrew J, Adams Dave J, Clifford Anthony A, Rayner Christopher M
机构信息
Department of Chemistry, University of Leeds, Leeds LS2 9JT, UK.
出版信息
Chem Commun (Camb). 2004 Dec 7(23):2720-1. doi: 10.1039/b409451d. Epub 2004 Oct 8.
DOI:10.1039/b409451d
PMID:15568084
Abstract
The rate and stereocontrol of the Henry reaction in the presence of CO(2) can be controlled simply by manipulation of CO(2) pressure, and can be understood by consideration of the kinetic and thermodynamic aspects of the reaction.
摘要
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