利用光热触发有机催化剂对亨利反应进行双重立体控制。
Dual stereocontrol over the Henry reaction using a light- and heat-triggered organocatalyst.
作者信息
Vlatković Matea, Bernardi Luca, Otten Edwin, Feringa Ben L
机构信息
Stratingh Institute for Chemistry, University of Groningen, Nijenborg 4, 9747 AG Groningen, The Netherlands.
出版信息
Chem Commun (Camb). 2014 Jul 25;50(58):7773-5. doi: 10.1039/c4cc00794h.
PMID:24667967
Abstract
Here we present a novel dynamic organocatalyst, based on a first-generation molecular motor core, able to control the stereochemical outcome of the Henry reaction using both light and heat as external stimuli.
摘要
在此，我们展示了一种基于第一代分子马达核心的新型动态有机催化剂，它能够利用光和热作为外部刺激来控制亨利反应的立体化学结果。
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