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圆珠笔油墨的年代测定。

Dating of ballpoint pen ink.

作者信息

Hofer R

机构信息

Forensic Science Division, Document Laboratory, Zurich Canton Police, 8021 Zurich, Switzerland.

出版信息

J Forensic Sci. 2004 Nov;49(6):1353-7.

Abstract

In this paper we describe a case in which a cash book, dated of the year 2000, was sent to the Forensic Science Division, Document Laboratory, Zurich Canton Police in March 2003. The questioned document was a list of 29 pages containing a consecutive handwritten numbering and dated entries (payments) made of blue ballpoint pen ink. By definition, a cash book has to be written by hand and the entries have to be made daily. The questioned document was suspected to have been written within a short period (e.g., a few hours) and backdated. The document lab was asked to determine the date of the entries of the questioned list. On one hand, we were asked, if the cash book had been kept on account consecutively during the period of one year, and on the other hand, the judges were interested in knowing, if the document could have been written in 2003 and back dated to 2000. To answer these questions, the document was examined for latent elements by electrostatic detection device (ESDA). The relative dating of the entries was performed by the quantification of the ballpoint pen ink dyes and their degradation products using HPLC. Results show that it is possible to determine the relative age of entries written by ballpoint pen within a relatively short time scale, if storage and supporting material of the different samples are the same or at least similar.

摘要

在本文中,我们描述了一个案例,一本日期为2000年的现金日记账于2003年3月被送交苏黎世州警察文件实验室法医科学部。该可疑文件是一份29页的清单,包含连续的手写编号以及用蓝色圆珠笔墨水记录的日期条目(付款记录)。根据定义,现金日记账必须手写,且条目必须每日记录。该可疑文件被怀疑是在短时间内(例如几个小时)写成并倒填日期的。文件实验室被要求确定该可疑清单条目的日期。一方面,我们被问及这本现金日记账在一年期间是否连续记账,另一方面,法官们想知道这份文件是否可能是在2003年写成并倒填到2000年的。为回答这些问题,使用静电检测装置(ESDA)对该文件进行潜在元素检查。通过使用高效液相色谱法对圆珠笔墨水染料及其降解产物进行定量分析来确定条目的相对日期。结果表明,如果不同样本的存储和支撑材料相同或至少相似,那么在相对较短的时间范围内确定圆珠笔书写条目的相对年代是可能的。

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