Gaebert Carsten, Siegner Christian, Mattay Jochen, Toubartz Marion, Steenken Steen
Organische Chemie I, Universitat Bielefeld, Universitatsstrasse 25, D-33615, Bielefeld, Germany.
Photochem Photobiol Sci. 2004 Nov-Dec;3(11-12):990-1. doi: 10.1039/b410464a. Epub 2004 Oct 7.
The radical cations of 1-butyl-trans-2,3-diphenyl aziridine (1), 1-butyl-2-phenyl aziridine (2), 1,2-diphenyl aziridine (3) and 1-(p-methoxyphenyl)-2-phenyl aziridine (4) were generated upon laser flash photolysis in aqueous and aqueous acetonitrile solutions by direct photoionisation as indicated by the broad absorption band of the solvated electron above 550 nm as well.
1-丁基-反式-2,3-二苯基氮丙啶(1)、1-丁基-2-苯基氮丙啶(2)、1,2-二苯基氮丙啶(3)和1-(对甲氧基苯基)-2-苯基氮丙啶(4)的自由基阳离子是通过激光闪光光解在水和乙腈水溶液中通过直接光电离产生的,550 nm以上溶剂化电子的宽吸收带也表明了这一点。