Zhou Hong, Zhang Xiao-Jian, Wang Zhan-Sheng
Institute of Civil Engineering, Guangzhou University, Guangzhou 510405, Guangdong, China.
Biomed Environ Sci. 2004 Sep;17(3):299-308.
Since haloacetic acids (HAAs), which are nonvolatile and of high carcinogenic risk, are common species of chlorinated disinfection by-products(DBPs) in drinking water, and little has been known in China, it is necessary to make a survey about the kinds and levels of HAAs in drinking water of the nation.
HAAs were analyzed using gas chromatography with electron capture detector(GC/ECD) and relatively complex pretreatment process of sample was applied. Five main cities in different areas of China were chosen in the survey.
Studies showed that the main species of HAAs in drinking water in China were DCAA and TCAA, ranging from 0.4 microg/L to 12.85 microg/L and from 0.56 microg/L to 10.98 microg/L, respectively. MBAA and DBAA were also detected in one city, ranging from 2.20 microg/L to 4.95 microg/L and 1.10 microg/L to 2.81 microg/L, respectively. Therefore, the contents of HAAs varied, usually no more than 25 microg/L. Based on the acquired data to date, it is known that the concentrations of HAAs in drinking water in China were surely under the limits of Sanitary Standard for Drinking Water Quality (China, 2001).
A wider survey of HAAs in drinking water should be conducted throughout the nation to get adequate data and information, the ultimate aim of which is to control HAAs pollution and keep the balance between microbiological safety insurance and chemical risk control, minimize the formation of DBPs and ensure the safety of water supply at the same time.
由于卤乙酸(HAAs)是饮用水中常见的氯化消毒副产物(DBPs),具有非挥发性且致癌风险高,而我国对此了解较少,因此有必要对全国饮用水中HAAs的种类和含量进行调查。
采用带电子捕获检测器的气相色谱法(GC/ECD)分析HAAs,并应用相对复杂的样品预处理过程。调查选取了中国不同地区的五个主要城市。
研究表明,我国饮用水中HAAs的主要种类为二氯乙酸(DCAA)和三氯乙酸(TCAA),含量分别为0.4微克/升至12.85微克/升和0.56微克/升至10.98微克/升。在一个城市中还检测到一溴乙酸(MBAA)和二溴乙酸(DBAA),含量分别为2.20微克/升至4.95微克/升和1.10微克/升至2.81微克/升。因此,HAAs的含量各不相同,通常不超过25微克/升。根据目前获得的数据,可知我国饮用水中HAAs的浓度肯定低于《生活饮用水卫生标准》(中国,2001年)的限值。
应在全国范围内对饮用水中的HAAs进行更广泛的调查,以获取足够的数据和信息,其最终目的是控制HAAs污染,保持微生物安全保障与化学风险控制之间的平衡,最大限度地减少消毒副产物的形成,同时确保供水安全。