钯[0]催化的乌尔曼交叉偶联反应在天然产物化学中的应用：用于生物碱（±）-阿朴菲啶的全合成
Exploiting the palladium[0]-catalysed Ullmann cross-coupling reaction in natural products chemistry: application to a total synthesis of the alkaloid (+/-)-aspidospermidine.
作者信息
Banwell Martin G, Lupton David W
机构信息
Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia.
出版信息
Org Biomol Chem. 2005 Jan 21;3(2):213-5. doi: 10.1039/b415977b. Epub 2004 Dec 7.
DOI:10.1039/b415977b
PMID:15632959
Abstract
Azide 14, available through the title cross-coupling process, has been converted, via the ring-fused aziridine 15, into the alkaloid aspidospermidine.
摘要
通过标题交叉偶联过程可得叠氮化物14，它已通过稠环氮丙啶15转化为生物碱阿朴长春胺酸。
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