一种用于己糖单糖不对称合成的超季铵乙醇酸酯羟醛缩合方法。
A SuperQuat glycolate aldol approach to the asymmetric synthesis of hexose monosaccharides.
作者信息
Davies Stephen G, Nicholson Rebecca L, Smith Andrew D
机构信息
The Department of Organic Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, UK OX1 3TA.
出版信息
Org Biomol Chem. 2005 Jan 21;3(2):348-59. doi: 10.1039/b415943h. Epub 2004 Dec 15.
DOI:10.1039/b415943h
PMID:15632978
Abstract
A stereoselective two-carbon homologation protocol has been developed and applied to the asymmetric synthesis of the hexose monosaccharides D-galactose, D-fucose, D-idose, D-6-deoxyidose, D-talose and D-6-deoxytalose.
摘要
已开发出一种立体选择性的双碳同系化方法，并将其应用于己糖单糖D-半乳糖、D-岩藻糖、D-艾杜糖、D-6-脱氧艾杜糖、D-塔罗糖和D-6-脱氧塔罗糖的不对称合成。
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