对磺基杯[6]芳烃对L-或D-亮氨酸的选择性单晶络合作用。
Selective single crystal complexation of L- or D-leucine by p-sulfonatocalix[6]arene.
作者信息
Atwood Jerry L, Dalgarno Scott J, Hardie Michaele J, Raston Colin L
机构信息
Department of Chemistry, University of Missouri-Columbia, Columbia, Missouri 65211, USA.
出版信息
Chem Commun (Camb). 2005 Jan 21(3):337-9. doi: 10.1039/b413821j. Epub 2004 Dec 13.
DOI:10.1039/b413821j
PMID:15645029
Abstract
p-Sulfonatocalix[6]arene, organised in the 'double cone' conformation, has multi-guest capability binding either L- or D-leucine in a single crystal in a bi-layer type arrangement from a racemic mixture of the amino acid.
摘要
对磺基杯[6]芳烃呈“双锥”构象，具有多客体容纳能力，能从氨基酸的外消旋混合物中以双层排列方式在单晶中结合L-亮氨酸或D-亮氨酸。
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