镧系元素诱导的[{Co(III) 穴状配体} 交叉 {对磺基杯[4]芳烃}]超分子螺旋阵列。
Lanthanide-induced helical arrays of [{Co(III) sepulchrate} intersection {p-sulfonatocalix[4]arene}] supermolecules.
作者信息
Smith Christopher B, Barbour Leonard J, Makha Mohamed, Raston Colin L, Sobolev Alexandre N
机构信息
School of Biomedical, Biomolecular and Chemical Sciences, University of Western Australia, Crawley, W.A. 6009, Australia.
出版信息
Chem Commun (Camb). 2006 Mar 7(9):950-2. doi: 10.1039/b515580k. Epub 2005 Dec 15.
DOI:10.1039/b515580k
PMID:16491172
Abstract
In the presence of lanthanide ions, a Co(III) sepulchrate cation [Co(diHOsar)]3+ and sodium p-sulfonatocalix[4]arene form a 1:1 host-guest complex which is self-assembled into a zeolite-like lattice network comprised of parallel, single stranded helices.
摘要
在镧系离子存在的情况下，穴状钴（III）阳离子[Co(diHOsar)]3+与对磺酸钠杯[4]芳烃形成1:1的主客体配合物，该配合物自组装成由平行单链螺旋组成的类沸石晶格网络。
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